Matches in DBpedia 2015-10 for { <http://dbpedia.org/resource/Dissociative_substitution> ?p ?o }
Showing triples 1 to 65 of
65
with 100 triples per page.
- Dissociative_substitution abstract "Dissociative substitution describes a pathway by which compounds interchange ligands. The term is typically applied to coordination and organometallic complexes, but resembles the Sn1 mechanism in organic chemistry. This pathway can be well described by the cis effect, or the labilization of CO ligands in the cis position. The opposite pathway is associative substitution, being analogous to Sn2 pathway. Intermediate pathways exist between the pure dissociative and pure associative pathways, these are called interchange mechanisms.Complexes that undergo dissociative substitution are often coordinatively saturated and often have octahedral molecular geometry. The entropy of activation is characteristically positive for these reactions, which indicates that the disorder of the reacting system increases in the rate determining step.".
- Dissociative_substitution thumbnail General_reaction_with_dissociative_mechanism.png?width=300.
- Dissociative_substitution wikiPageID "21844293".
- Dissociative_substitution wikiPageLength "5813".
- Dissociative_substitution wikiPageOutDegree "27".
- Dissociative_substitution wikiPageRevisionID "648332649".
- Dissociative_substitution wikiPageWikiLink Aquo_complex.
- Dissociative_substitution wikiPageWikiLink Associative_substitution.
- Dissociative_substitution wikiPageWikiLink Category:Chemical_reactions.
- Dissociative_substitution wikiPageWikiLink Category:Coordination_chemistry.
- Dissociative_substitution wikiPageWikiLink Category:Organometallic_chemistry.
- Dissociative_substitution wikiPageWikiLink Category:Reaction_mechanisms.
- Dissociative_substitution wikiPageWikiLink Cation.
- Dissociative_substitution wikiPageWikiLink Cis_effect.
- Dissociative_substitution wikiPageWikiLink Conjugate_acid.
- Dissociative_substitution wikiPageWikiLink Conjugate_base.
- Dissociative_substitution wikiPageWikiLink Coordination_chemistry.
- Dissociative_substitution wikiPageWikiLink Coordination_complex.
- Dissociative_substitution wikiPageWikiLink Coordinative_unsaturation.
- Dissociative_substitution wikiPageWikiLink Entropy_of_activation.
- Dissociative_substitution wikiPageWikiLink Hydrolysis.
- Dissociative_substitution wikiPageWikiLink Interchange_mechanism.
- Dissociative_substitution wikiPageWikiLink Ion.
- Dissociative_substitution wikiPageWikiLink Ligand.
- Dissociative_substitution wikiPageWikiLink Magnetic_resonance_imaging.
- Dissociative_substitution wikiPageWikiLink Metal_aquo_complex.
- Dissociative_substitution wikiPageWikiLink Nucleophile.
- Dissociative_substitution wikiPageWikiLink Octahedral_molecular_geometry.
- Dissociative_substitution wikiPageWikiLink Organic_chemistry.
- Dissociative_substitution wikiPageWikiLink Organometallic_chemistry.
- Dissociative_substitution wikiPageWikiLink Rate-determining_step.
- Dissociative_substitution wikiPageWikiLink Rate_constant.
- Dissociative_substitution wikiPageWikiLink Rate_determining_step.
- Dissociative_substitution wikiPageWikiLink Reaction_rate_constant.
- Dissociative_substitution wikiPageWikiLink SN1_reaction.
- Dissociative_substitution wikiPageWikiLink SN2_reaction.
- Dissociative_substitution wikiPageWikiLink Saturation_(chemistry).
- Dissociative_substitution wikiPageWikiLink Sn1CB_mechanism.
- Dissociative_substitution wikiPageWikiLink Thiocyanate.
- Dissociative_substitution wikiPageWikiLink File:General_reaction_with_dissociative_mechanism.png.
- Dissociative_substitution wikiPageWikiLinkText "Dissociative substitution".
- Dissociative_substitution wikiPageWikiLinkText "dissociation pathway".
- Dissociative_substitution wikiPageWikiLinkText "dissociative interchange".
- Dissociative_substitution wikiPageWikiLinkText "dissociative mechanism".
- Dissociative_substitution wikiPageWikiLinkText "dissociative or solvent assisted".
- Dissociative_substitution wikiPageWikiLinkText "dissociative substitution".
- Dissociative_substitution wikiPageWikiLinkText "dissociative".
- Dissociative_substitution hasPhotoCollection Dissociative_substitution.
- Dissociative_substitution wikiPageUsesTemplate Template:Eqm.
- Dissociative_substitution wikiPageUsesTemplate Template:Redirect.
- Dissociative_substitution subject Category:Chemical_reactions.
- Dissociative_substitution subject Category:Coordination_chemistry.
- Dissociative_substitution subject Category:Organometallic_chemistry.
- Dissociative_substitution subject Category:Reaction_mechanisms.
- Dissociative_substitution type Process.
- Dissociative_substitution type Reaction.
- Dissociative_substitution comment "Dissociative substitution describes a pathway by which compounds interchange ligands. The term is typically applied to coordination and organometallic complexes, but resembles the Sn1 mechanism in organic chemistry. This pathway can be well described by the cis effect, or the labilization of CO ligands in the cis position. The opposite pathway is associative substitution, being analogous to Sn2 pathway.".
- Dissociative_substitution label "Dissociative substitution".
- Dissociative_substitution sameAs Sustitución_disociativa.
- Dissociative_substitution sameAs m.05p1qh1.
- Dissociative_substitution sameAs Q5282795.
- Dissociative_substitution sameAs Q5282795.
- Dissociative_substitution wasDerivedFrom Dissociative_substitution?oldid=648332649.
- Dissociative_substitution depiction General_reaction_with_dissociative_mechanism.png.
- Dissociative_substitution isPrimaryTopicOf Dissociative_substitution.