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- Carbenoid abstract "In chemistry a carbenoid is a reactive intermediate that shares reaction characteristics with a carbene. In the Simmons–Smith reaction the carbenoid intermediate is a zinc / iodine complex that takes the form ofI-CH2-Zn-IThis complex reacts with an alkene to form a cyclopropane just as a carbene would do.Carbenoids appear as intermediates in many other reactions. In one system a carbenoid chloroalkyllithium reagent is prepared in situ from a sulfoxide and t-BuLi which reacts the boronic ester to give an ate complex. The ate complex undergoes a 1,2-metallate rearrangement to give the homologated product, which is then further oxidised to a secondary alcohol.Insertion of carbenoid into C-B bondThe enantiopurity of the chiral sulfoxide is preserved in the ultimate product after oxidation of the boronic ester to the alcohol indicating that a true carbene was never involved in the sequence.".
- Carbenoid thumbnail CarbenoidApplication.png?width=300.
- Carbenoid wikiPageID "1693124".
- Carbenoid wikiPageLength "1541".
- Carbenoid wikiPageOutDegree "16".
- Carbenoid wikiPageRevisionID "559734838".
- Carbenoid wikiPageWikiLink Alcohol.
- Carbenoid wikiPageWikiLink Alkene.
- Carbenoid wikiPageWikiLink Carbene.
- Carbenoid wikiPageWikiLink Category:Carbenes.
- Carbenoid wikiPageWikiLink Chemistry.
- Carbenoid wikiPageWikiLink Complex_(chemistry).
- Carbenoid wikiPageWikiLink Coordination_complex.
- Carbenoid wikiPageWikiLink Cyclopropane.
- Carbenoid wikiPageWikiLink Enantiomer.
- Carbenoid wikiPageWikiLink Enantiopurity.
- Carbenoid wikiPageWikiLink Iodine.
- Carbenoid wikiPageWikiLink Organolithium.
- Carbenoid wikiPageWikiLink Organolithium_reagent.
- Carbenoid wikiPageWikiLink Reactive_intermediate.
- Carbenoid wikiPageWikiLink Silylenoid.
- Carbenoid wikiPageWikiLink Simmons–Smith_reaction.
- Carbenoid wikiPageWikiLink Sulfoxide.
- Carbenoid wikiPageWikiLink Zinc.
- Carbenoid wikiPageWikiLink File:CarbenoidApplication.png.
- Carbenoid wikiPageWikiLinkText "Carbenoid".
- Carbenoid wikiPageWikiLinkText "carbenoid".
- Carbenoid hasPhotoCollection Carbenoid.
- Carbenoid wikiPageUsesTemplate Template:Reflist.
- Carbenoid subject Category:Carbenes.
- Carbenoid comment "In chemistry a carbenoid is a reactive intermediate that shares reaction characteristics with a carbene. In the Simmons–Smith reaction the carbenoid intermediate is a zinc / iodine complex that takes the form ofI-CH2-Zn-IThis complex reacts with an alkene to form a cyclopropane just as a carbene would do.Carbenoids appear as intermediates in many other reactions.".
- Carbenoid label "Carbenoid".
- Carbenoid sameAs Carbenoide.
- Carbenoid sameAs Karbenoidit.
- Carbenoid sameAs m.05nwl3.
- Carbenoid sameAs Q1035476.
- Carbenoid sameAs Q1035476.
- Carbenoid wasDerivedFrom Carbenoid?oldid=559734838.
- Carbenoid depiction CarbenoidApplication.png.
- Carbenoid isPrimaryTopicOf Carbenoid.