Matches in DBpedia 2015-10 for { <http://dbpedia.org/resource/Bicyclopropenyl> ?p ?o }
Showing triples 1 to 67 of
67
with 100 triples per page.
- Bicyclopropenyl abstract "Bicyclopropenyl (bicycloprop-2-enyl, C6H6) is an organic compound and one of several valence isomers of benzene. The molecule can be described as two coupled cyclopropene units. The positions of the alkene groups can vary and therefore two other isomers are known: bicycloprop-1,2-enyl and bicyclopropen-1-yl. bicycloprop-2-enyl, bicycloprop-1-enyl and bicycloprop-1,2-enylThe synthesis of all three isomers was reported in 1989 By Billups and Haley. The 3,3 isomer was formed in two steps by reaction of 1,4-bis(trimethylsilyl)buta-1,3-diene with methyllithium and dichloromethane, introducing two cyclopropane rings into the molecule. The bis(2-chloro-3-(trimethylsilyl)cyclopropan-1-yl) formed is reacted with TBAF. In this latter reaction fluoride couples to the trimethylsilyl group, in the process forming the double bond and forcing the chlorine atom to leave as chloride. In presence of silver ions bicycloprop-2-enyl rearranges to Dewar benzene. The compound can also be trapped by cyclopentadiene. Above -10 °C it decomposes with polymerization. An X-ray crystal structure has been reported. The bond length for the central bond is short by 1.503 Ångström (150.3 pm). The other two isomers are increasingly unstable. Bicycloprop-1-enyl can only be detected in trapping experiments.".
- Bicyclopropenyl iupacName "Bicycloprop-2-enyl".
- Bicyclopropenyl thumbnail Bicycloprop-2-enyl.svg?width=300.
- Bicyclopropenyl wikiPageID "26568465".
- Bicyclopropenyl wikiPageLength "4423".
- Bicyclopropenyl wikiPageOutDegree "23".
- Bicyclopropenyl wikiPageRevisionID "678444660".
- Bicyclopropenyl wikiPageWikiLink Alkene.
- Bicyclopropenyl wikiPageWikiLink Angstrom.
- Bicyclopropenyl wikiPageWikiLink Benzene.
- Bicyclopropenyl wikiPageWikiLink Benzvalene.
- Bicyclopropenyl wikiPageWikiLink Bond_length.
- Bicyclopropenyl wikiPageWikiLink Category:Alkenes.
- Bicyclopropenyl wikiPageWikiLink Cyclopentadiene.
- Bicyclopropenyl wikiPageWikiLink Cyclopropene.
- Bicyclopropenyl wikiPageWikiLink Dewar_benzene.
- Bicyclopropenyl wikiPageWikiLink Dichloromethane.
- Bicyclopropenyl wikiPageWikiLink Heat_of_formation.
- Bicyclopropenyl wikiPageWikiLink Methyllithium.
- Bicyclopropenyl wikiPageWikiLink Organic_compound.
- Bicyclopropenyl wikiPageWikiLink Picometer.
- Bicyclopropenyl wikiPageWikiLink Picometre.
- Bicyclopropenyl wikiPageWikiLink Polymerization.
- Bicyclopropenyl wikiPageWikiLink Prismane.
- Bicyclopropenyl wikiPageWikiLink Silver.
- Bicyclopropenyl wikiPageWikiLink Standard_enthalpy_of_formation.
- Bicyclopropenyl wikiPageWikiLink TBAF.
- Bicyclopropenyl wikiPageWikiLink Tetra-n-butylammonium_fluoride.
- Bicyclopropenyl wikiPageWikiLink Valence_isomer.
- Bicyclopropenyl wikiPageWikiLink X-ray_crystal_structure.
- Bicyclopropenyl wikiPageWikiLink X-ray_crystallography.
- Bicyclopropenyl wikiPageWikiLink Ångström.
- Bicyclopropenyl wikiPageWikiLink File:Bicyclopropenyl.svg.
- Bicyclopropenyl wikiPageWikiLinkText "Bicyclopropenyl".
- Bicyclopropenyl hasPhotoCollection Bicyclopropenyl.
- Bicyclopropenyl imagefile "33".
- Bicyclopropenyl imagefile "Bicycloprop-2-enyl.svg".
- Bicyclopropenyl imagesize "100".
- Bicyclopropenyl iupacname "Bicycloprop-2-enyl".
- Bicyclopropenyl othernames "33".
- Bicyclopropenyl verifiedfields "changed".
- Bicyclopropenyl verifiedrevid "426240665".
- Bicyclopropenyl watchedfields "changed".
- Bicyclopropenyl wikiPageUsesTemplate Template:Chembox.
- Bicyclopropenyl wikiPageUsesTemplate Template:Reflist.
- Bicyclopropenyl subject Category:Alkenes.
- Bicyclopropenyl hypernym Compound.
- Bicyclopropenyl type ChemicalCompound.
- Bicyclopropenyl type ChemicalSubstance.
- Bicyclopropenyl type Alkene.
- Bicyclopropenyl type Hydrocarbon.
- Bicyclopropenyl type ChemicalObject.
- Bicyclopropenyl type Thing.
- Bicyclopropenyl type Q11173.
- Bicyclopropenyl comment "Bicyclopropenyl (bicycloprop-2-enyl, C6H6) is an organic compound and one of several valence isomers of benzene. The molecule can be described as two coupled cyclopropene units. The positions of the alkene groups can vary and therefore two other isomers are known: bicycloprop-1,2-enyl and bicyclopropen-1-yl. bicycloprop-2-enyl, bicycloprop-1-enyl and bicycloprop-1,2-enylThe synthesis of all three isomers was reported in 1989 By Billups and Haley.".
- Bicyclopropenyl label "Bicyclopropenyl".
- Bicyclopropenyl sameAs بیسیکلوپروپنیل.
- Bicyclopropenyl sameAs Bicycloprop-2-enyl.
- Bicyclopropenyl sameAs m.0bh8w9x.
- Bicyclopropenyl sameAs Biciklopropenil.
- Bicyclopropenyl sameAs Biciklopropenil.
- Bicyclopropenyl sameAs Q1083122.
- Bicyclopropenyl sameAs Q1083122.
- Bicyclopropenyl sameAs 联环丙烯.
- Bicyclopropenyl wasDerivedFrom Bicyclopropenyl?oldid=678444660.
- Bicyclopropenyl depiction Bicycloprop-2-enyl.svg.
- Bicyclopropenyl isPrimaryTopicOf Bicyclopropenyl.