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3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate abstract "3-Deoxy-D-arabino-heptulosonic acid 7-phosphate (DAHP) is a 7-carbon ulonic acid. This compound is found in the shikimic acid biosynthesis pathway and is an intermediate in the production of aromatic amino acids.Phosphoenolpyruvate and erythrose-4-phosphate react to form 3-deoxy-D-arabinoheptulosonate-7-phosphate (DAHP), in a reaction catalyzed by the enzyme DAHP synthase. DAHP is then transformed to 3-dehydroquinate (DHQ), in a reaction catalyzed by DHQ synthase. Although this reaction requires nicotinamide adenine dinucleotide (NAD) as a cofactor, the enzymic mechanism regenerates it, resulting in the net use of no NAD.The mechanism of ring closure is complex, but involves an aldol condensation at C-2 and C-7. Metabolic engineering has improved production of DAHP by Escherichia coli. The first step, condensation of 3-deoxy-D-arabino-heptulosonic acid 7-phosphate (DAHP) from PEP/E4P, uses three isoenzymes AroF, AroG, and AroH. Each one of these has its synthesis regulated from tyrosine, phenylalanine, and tryptophan, respectively. These isoenzymes all have the ability to help regulate synthesis of DAHP by the method of feedback inhibition. This acts in the cell by monitoring the concentrations of each of the three aromatic amino acids. When there is too much of any one of them, that one will allosterically control the DAHP synthetase by “turning it off”. With the first step of the common pathway shut off, synthesis of the three amino acids can not proceed. The rest of the enzymes is in the common pathway (conversion of DAHP to chorismate).↑ ↑".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate iupacName "(4R,5S,6R)-4,5,6-Trihydroxy-2-oxo-7-phosphonooxyheptanoic acid".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate thumbnail 3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate_(DAHP).png?width=300.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageID "38144618".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageLength "5176".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageOutDegree "20".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageRevisionID "670407196".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink 3-Dehydroquinic_acid.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink 3-dehydroquinate_synthase.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Aldol_condensation.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Amino_acid_synthesis.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Category:Carboxylic_acids.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Category:Heptoses.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Category:Monosaccharide_derivatives.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Category:Organophosphates.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Cyclic_compound.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink DAHP_synthase.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink DHQ_synthase.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Erythrose-4-phosphate.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Erythrose_4-phosphate.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Escherichia_coli.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Metabolic_engineering.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Nicotinamide_adenine_dinucleotide.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Phosphoenolpyruvate.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Phosphoenolpyruvic_acid.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Ring_closure.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Shikimate_pathway.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Shikimic_acid_pathway.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink Ulonic_acid.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink File:DAHP_pathway.jpg.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink File:DAHP_synthase_reaction.svg.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLink File:Reaction_catalyzed_by_3-dehydroquinate_synthase.svg.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageWikiLinkText "3-Deoxy-D-arabino-heptulosonic acid 7-phosphate".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate hasPhotoCollection 3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate imagealt "Chemical structure of 3-deoxy-D-arabino-heptulosonic acid 7-phosphate .".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate imagefile "3".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate imagesize "100".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate iupacname "-456".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate name "3".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate othernames "3".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate othernames "7".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate othernames "DAHP".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageUsesTemplate Template:Chembox.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageUsesTemplate Template:Cite_journal.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageUsesTemplate Template:Clear-left.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wikiPageUsesTemplate Template:Reflist.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate subject Category:Carboxylic_acids.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate subject Category:Heptoses.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate subject Category:Monosaccharide_derivatives.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate subject Category:Organophosphates.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Article.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type ChemicalCompound.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type ChemicalSubstance.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Group.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Article.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Chemical.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Ester.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Group.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Monosaccharide.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Organophosphate.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Organophosphoru.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Organophosphate.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Organophosphoru.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type ChemicalObject.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Thing.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate type Q11173.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate comment "3-Deoxy-D-arabino-heptulosonic acid 7-phosphate (DAHP) is a 7-carbon ulonic acid. This compound is found in the shikimic acid biosynthesis pathway and is an intermediate in the production of aromatic amino acids.Phosphoenolpyruvate and erythrose-4-phosphate react to form 3-deoxy-D-arabinoheptulosonate-7-phosphate (DAHP), in a reaction catalyzed by the enzyme DAHP synthase. DAHP is then transformed to 3-dehydroquinate (DHQ), in a reaction catalyzed by DHQ synthase.".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate label "3-Deoxy-D-arabino-heptulosonic acid 7-phosphate".
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate sameAs Acido_3-deossi-D-arabino-eptulosonico_7-fosfato.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate sameAs m.0pdnbsj.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate sameAs 3-Dezoksi-D-arabino-heptulosonska_kiselina_7-fosfat.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate sameAs 3-Dezoksi-D-arabino-heptulosonska_kiselina_7-fosfat.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate sameAs Q2690247.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate sameAs Q2690247.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate sameAs 3-脱氧-D-阿糖基庚糖酮酸-7-磷酸.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate wasDerivedFrom 3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate?oldid=670407196.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate depiction 3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate_(DAHP).png.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate isPrimaryTopicOf 3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate.
3-Deoxy-D-arabino-heptulosonic_acid_7-phosphate name "3-Deoxy-(D)-arabino-heptulosonic acid 7-phosphate".