Matches in DBpedia 2015-10 for { <http://dbpedia.org/resource/18-Electron_rule> ?p ?o }
- 18-Electron_rule abstract "The 18-electron rule is a rule used primarily for predicting formulae for stable metal complexes. The rule is based on the fact that the valence shells of transition metals consist of nine valence orbitals, which collectively can accommodate 18 electrons as either bonding or nonbonding electron pairs. This means that, the combination of these nine atomic orbitals with ligand orbitals creates nine molecular orbitals that are either metal-ligand bonding or non-bonding. When a metal complex has 18 valence electrons, it is said to have achieved the same electron configuration as the noble gas in the period. The rule and its exceptions are similar to the application of the octet rule to main group elements. The rule is not helpful for complexes of metals that are not transition metals, and interesting or useful transition metal complexes will violate the rule because of the consequences deviating from the rule bears on reactivity. The rule was first proposed by American chemist Irving Langmuir in 1921.".
- 18-Electron_rule wikiPageID "5170027".
- 18-Electron_rule wikiPageLength "13100".
- 18-Electron_rule wikiPageOutDegree "61".
- 18-Electron_rule wikiPageRevisionID "681498417".
- 18-Electron_rule wikiPageWikiLink Alkene.
- 18-Electron_rule wikiPageWikiLink Atomic_orbital.
- 18-Electron_rule wikiPageWikiLink Atomic_orbitals.
- 18-Electron_rule wikiPageWikiLink Basis_set_(chemistry).
- 18-Electron_rule wikiPageWikiLink Carbonyl.
- 18-Electron_rule wikiPageWikiLink Catalysis.
- 18-Electron_rule wikiPageWikiLink Catalytic_cycle.
- 18-Electron_rule wikiPageWikiLink Category:Chemical_bonding.
- 18-Electron_rule wikiPageWikiLink Category:Empirical_laws.
- 18-Electron_rule wikiPageWikiLink Category:Inorganic_chemistry.
- 18-Electron_rule wikiPageWikiLink Chem._Soc._Rev..
- 18-Electron_rule wikiPageWikiLink Chemical_Society_Reviews.
- 18-Electron_rule wikiPageWikiLink Chromium_carbonyl.
- 18-Electron_rule wikiPageWikiLink Chromium_hexacarbonyl.
- 18-Electron_rule wikiPageWikiLink Cobaltocene.
- 18-Electron_rule wikiPageWikiLink D_electron_count.
- 18-Electron_rule wikiPageWikiLink Dissociative_substitution.
- 18-Electron_rule wikiPageWikiLink Electron.
- 18-Electron_rule wikiPageWikiLink Electron_counting.
- 18-Electron_rule wikiPageWikiLink Electron_shell.
- 18-Electron_rule wikiPageWikiLink Ferrocene.
- 18-Electron_rule wikiPageWikiLink Ferrocyanide.
- 18-Electron_rule wikiPageWikiLink Hexamminecobalt(III)_chloride.
- 18-Electron_rule wikiPageWikiLink Hydroformylation.
- 18-Electron_rule wikiPageWikiLink Hydrogenation.
- 18-Electron_rule wikiPageWikiLink Hypervalent_molecule.
- 18-Electron_rule wikiPageWikiLink Iron_pentacarbonyl.
- 18-Electron_rule wikiPageWikiLink Irving_Langmuir.
- 18-Electron_rule wikiPageWikiLink Ligand.
- 18-Electron_rule wikiPageWikiLink Ligand_field.
- 18-Electron_rule wikiPageWikiLink Ligand_field_theory.
- 18-Electron_rule wikiPageWikiLink Molecular_orbital.
- 18-Electron_rule wikiPageWikiLink Molybdenum_carbonyl.
- 18-Electron_rule wikiPageWikiLink Molybdenum_hexacarbonyl.
- 18-Electron_rule wikiPageWikiLink Monsanto_acetic_acid_synthesis.
- 18-Electron_rule wikiPageWikiLink Monsanto_process.
- 18-Electron_rule wikiPageWikiLink Nickel_carbonyl.
- 18-Electron_rule wikiPageWikiLink Nickel_tetracarbonyl.
- 18-Electron_rule wikiPageWikiLink Nickelocene.
- 18-Electron_rule wikiPageWikiLink Noble_gas.
- 18-Electron_rule wikiPageWikiLink Non-bonding_orbital.
- 18-Electron_rule wikiPageWikiLink Octahedral_molecular_geometry.
- 18-Electron_rule wikiPageWikiLink Octet_rule.
- 18-Electron_rule wikiPageWikiLink Olefin.
- 18-Electron_rule wikiPageWikiLink Oxidation_number.
- 18-Electron_rule wikiPageWikiLink Oxidation_state.
- 18-Electron_rule wikiPageWikiLink Oxygen.
- 18-Electron_rule wikiPageWikiLink Pentamethylcyclopentadiene.
- 18-Electron_rule wikiPageWikiLink Phosphine.
- 18-Electron_rule wikiPageWikiLink Phosphines.
- 18-Electron_rule wikiPageWikiLink Pi-acceptor_ligand.
- 18-Electron_rule wikiPageWikiLink Pi_backbonding.
- 18-Electron_rule wikiPageWikiLink Spectrochemical_series.
- 18-Electron_rule wikiPageWikiLink Spin_states_(d_electrons).
- 18-Electron_rule wikiPageWikiLink Square-planar.
- 18-Electron_rule wikiPageWikiLink Square_planar_molecular_geometry.
- 18-Electron_rule wikiPageWikiLink Stoichiometric.
- 18-Electron_rule wikiPageWikiLink Stoichiometry.
- 18-Electron_rule wikiPageWikiLink Tetrahedral_molecular_geometry.
- 18-Electron_rule wikiPageWikiLink Titanium(IV)_chloride.
- 18-Electron_rule wikiPageWikiLink Titanium_tetrachloride.
- 18-Electron_rule wikiPageWikiLink Tolmans_rule.
- 18-Electron_rule wikiPageWikiLink Transition_metal.
- 18-Electron_rule wikiPageWikiLink Valence_shell.
- 18-Electron_rule wikiPageWikiLink Vaskas_complex.
- 18-Electron_rule wikiPageWikiLink Zeises_salt.
- 18-Electron_rule wikiPageWikiLink Π_backbonding.
- 18-Electron_rule wikiPageWikiLink File:Chem507f09sqvstet2.png.
- 18-Electron_rule wikiPageWikiLinkText "18 electron".
- 18-Electron_rule wikiPageWikiLinkText "18-Electron rule".
- 18-Electron_rule wikiPageWikiLinkText "18-electron coordination compounds".
- 18-Electron_rule wikiPageWikiLinkText "18-electron rule".
- 18-Electron_rule wikiPageWikiLinkText "18-electron".
- 18-Electron_rule wikiPageWikiLinkText "Eighteen electron rule".
- 18-Electron_rule wikiPageWikiLinkText "Electron counting".
- 18-Electron_rule wikiPageWikiLinkText "unsaturated coordination sphere".
- 18-Electron_rule hasPhotoCollection 18-Electron_rule.
- 18-Electron_rule wikiPageUsesTemplate Template:Cite_journal.
- 18-Electron_rule wikiPageUsesTemplate Template:Organometallics.
- 18-Electron_rule wikiPageUsesTemplate Template:Reflist.
- 18-Electron_rule subject Category:Chemical_bonding.
- 18-Electron_rule subject Category:Empirical_laws.
- 18-Electron_rule subject Category:Inorganic_chemistry.
- 18-Electron_rule hypernym Rule.
- 18-Electron_rule type AdministrativeRegion.
- 18-Electron_rule type Law.
- 18-Electron_rule comment "The 18-electron rule is a rule used primarily for predicting formulae for stable metal complexes. The rule is based on the fact that the valence shells of transition metals consist of nine valence orbitals, which collectively can accommodate 18 electrons as either bonding or nonbonding electron pairs. This means that, the combination of these nine atomic orbitals with ligand orbitals creates nine molecular orbitals that are either metal-ligand bonding or non-bonding.".
- 18-Electron_rule label "18-Electron rule".
- 18-Electron_rule sameAs Regla_dels_18_electrons.
- 18-Electron_rule sameAs 18-Elektronen-Regel.
- 18-Electron_rule sameAs Regla_de_los_18_electrones.
- 18-Electron_rule sameAs 18_elektronin_sääntö.
- 18-Electron_rule sameAs Règle_des_18_électrons.
- 18-Electron_rule sameAs חוק_18_האלקטרונים.
- 18-Electron_rule sameAs Regola_dei_18_elettroni.