Matches in DBpedia 2016-04 for { ?s ?p "The Krapcho decarboxylation is the chemical reaction of esters with halide anions. The ester must contain an electron-withdrawing group in the beta position, such as β-ketoesters, malonic esters, α-cyanoesters, or α-sulfonylesters. It works best with methyl esters, since it is an SN2-reaction at carbon. It is driven by the entropy of the overall reaction, as the byproducts chloromethane and CO2 are lost as gases."@en }
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- Krapcho_decarboxylation comment "The Krapcho decarboxylation is the chemical reaction of esters with halide anions. The ester must contain an electron-withdrawing group in the beta position, such as β-ketoesters, malonic esters, α-cyanoesters, or α-sulfonylesters. It works best with methyl esters, since it is an SN2-reaction at carbon. It is driven by the entropy of the overall reaction, as the byproducts chloromethane and CO2 are lost as gases.".
- Q4597398 comment "The Krapcho decarboxylation is the chemical reaction of esters with halide anions. The ester must contain an electron-withdrawing group in the beta position, such as β-ketoesters, malonic esters, α-cyanoesters, or α-sulfonylesters. It works best with methyl esters, since it is an SN2-reaction at carbon. It is driven by the entropy of the overall reaction, as the byproducts chloromethane and CO2 are lost as gases.".