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- Manganese(III)_acetate abstract "Manganese(III) acetate is an inorganic compound that is used as an oxidizing agent in organic synthesis and materials science. Like the analogous acetates of iron and chromium, it is an oxygen-centered coordination complex containing three manganese atoms bridged by acetate units. The anhydrous form of this compound crystallizes as a linear coordination polymer, with an additional acetic acid molecule bridging between manganese atoms on consecutive three-manganese clusters. The chemical is therefore not a simple metal acetate ionic compound nor does the actual structure of it reflect the simple "Mn(OAc)3" chemical formula that is commonly given. It is usually used as the dihydrate, though the anhydrous form is also used in some situations. The dihydrate is prepared by reacting potassium permanganate and manganese(II) acetate in acetic acid; addition of acetic anhydride to the reaction produces the anhydrous form. It is also synthesized by electrochemical method starting from Mn(OAc)2.Mangese triacetate has been used as a single electron oxidant. It can oxidize alkenes via addition of acetic acid to form lactones.300pxThis process is thought to proceed via the formation of a •CH2CO2H radical intermediate, which then reacts with the alkene, followed by additional oxidation steps and finally ring closure. When the alkene is not symmetric, the major product depends on the nature of the alkene, and is consistent with initial formation of the more stable radical (among the two carbons of the alkene) followed by ring closure onto the more stable conformation of the intermediate.When reacted with enones, the carbon on the other side of the carbonyl reacts rather than the alkene portion, leading to α'-acetoxy enones. In this process, the carbon next to the carbonyl is oxidized by the manganese, followed by transfer of acetate from the manganese to it.It can similarly oxidize β-ketoesters at the α carbon, and this intermediate can react with various other structures, including halides and alkenes (see: manganese-mediated coupling reactions). One extension of this idea is the cyclization of the ketoester portion of the molecule with an alkene elsewhere in the same structure.".
- Manganese(III)_acetate iupacName "Manganese triacetate".
- Manganese(III)_acetate thumbnail Mn3O(OAc)6.png?width=300.
- Manganese(III)_acetate wikiPageID "13491397".
- Manganese(III)_acetate wikiPageLength "6495".
- Manganese(III)_acetate wikiPageOutDegree "24".
- Manganese(III)_acetate wikiPageRevisionID "672254248".
- Manganese(III)_acetate wikiPageWikiLink Acetate.
- Manganese(III)_acetate wikiPageWikiLink Acetic_acid.
- Manganese(III)_acetate wikiPageWikiLink Acetic_anhydride.
- Manganese(III)_acetate wikiPageWikiLink Acetoxy_group.
- Manganese(III)_acetate wikiPageWikiLink Category:Acetates.
- Manganese(III)_acetate wikiPageWikiLink Category:Manganese_compounds.
- Manganese(III)_acetate wikiPageWikiLink Category:Oxidizing_agents.
- Manganese(III)_acetate wikiPageWikiLink Chemical_formula.
- Manganese(III)_acetate wikiPageWikiLink Coordination_complex.
- Manganese(III)_acetate wikiPageWikiLink Coordination_polymer.
- Manganese(III)_acetate wikiPageWikiLink Enone.
- Manganese(III)_acetate wikiPageWikiLink Inorganic_compound.
- Manganese(III)_acetate wikiPageWikiLink Ionic_compound.
- Manganese(III)_acetate wikiPageWikiLink Lactone.
- Manganese(III)_acetate wikiPageWikiLink Manganese.
- Manganese(III)_acetate wikiPageWikiLink Manganese(II)_acetate.
- Manganese(III)_acetate wikiPageWikiLink Manganese-mediated_coupling_reactions.
- Manganese(III)_acetate wikiPageWikiLink Materials_science.
- Manganese(III)_acetate wikiPageWikiLink Organic_synthesis.
- Manganese(III)_acetate wikiPageWikiLink Oxidizing_agent.
- Manganese(III)_acetate wikiPageWikiLink Potassium_permanganate.
- Manganese(III)_acetate wikiPageWikiLink Radical_(chemistry).
- Manganese(III)_acetate wikiPageWikiLink File:Manganese_acetate_lactone_generic.png.
- Manganese(III)_acetate wikiPageWikiLinkText "".
- Manganese(III)_acetate wikiPageWikiLinkText "Manganese(III) acetate".
- Manganese(III)_acetate wikiPageWikiLinkText "manganese(III) acetate".
- Manganese(III)_acetate hasPhotoCollection Manganese(III)_acetate.
- Manganese(III)_acetate imagefile "Mn3O6.png".
- Manganese(III)_acetate iupacname "Manganese triacetate".
- Manganese(III)_acetate name "Manganese Triacetate".
- Manganese(III)_acetate othernames "Manganese triacetate dihydrate; Manganese acetate dihydrate".
- Manganese(III)_acetate verifiedfields "changed".
- Manganese(III)_acetate verifiedrevid "400295665".
- Manganese(III)_acetate watchedfields "changed".
- Manganese(III)_acetate wikiPageUsesTemplate Template:Acetates.
- Manganese(III)_acetate wikiPageUsesTemplate Template:Chembox.
- Manganese(III)_acetate wikiPageUsesTemplate Template:Clear.
- Manganese(III)_acetate subject Category:Acetates.
- Manganese(III)_acetate subject Category:Manganese_compounds.
- Manganese(III)_acetate subject Category:Oxidizing_agents.
- Manganese(III)_acetate hypernym Compound.
- Manganese(III)_acetate type ChemicalCompound.
- Manganese(III)_acetate type ChemicalSubstance.
- Manganese(III)_acetate type ChemicalObject.
- Manganese(III)_acetate type Thing.
- Manganese(III)_acetate type Q11173.
- Manganese(III)_acetate comment "Manganese(III) acetate is an inorganic compound that is used as an oxidizing agent in organic synthesis and materials science. Like the analogous acetates of iron and chromium, it is an oxygen-centered coordination complex containing three manganese atoms bridged by acetate units. The anhydrous form of this compound crystallizes as a linear coordination polymer, with an additional acetic acid molecule bridging between manganese atoms on consecutive three-manganese clusters.".
- Manganese(III)_acetate label "Manganese(III) acetate".
- Manganese(III)_acetate sameAs Mangan(III)-acetat.
- Manganese(III)_acetate sameAs Acetato_de_manganês(III).
- Manganese(III)_acetate sameAs m.03c729m.
- Manganese(III)_acetate sameAs Ацетат_марганца(III).
- Manganese(III)_acetate sameAs Mangan(III)_acetat.
- Manganese(III)_acetate sameAs Mangan(III)_acetat.
- Manganese(III)_acetate sameAs Q906315.
- Manganese(III)_acetate sameAs Q906315.
- Manganese(III)_acetate sameAs 乙酸锰(III).
- Manganese(III)_acetate wasDerivedFrom Manganese(III)_acetate?oldid=672254248.
- Manganese(III)_acetate depiction Mn3O(OAc)6.png.
- Manganese(III)_acetate isPrimaryTopicOf Manganese(III)_acetate.
- Manganese(III)_acetate name "Manganese Triacetate".