Matches in DBpedia 2016-04 for { ?s ?p "Dirigent Proteins are members of a class of proteins which dictate the stereochemistry of a compound synthesized by other enzymes. The first dirigent protein was discovered in Forsythia intermedia. This protein has been found to direct the stereoselective biosynthesis of (+)-pinoresinol from coniferyl alcohol monomers:Reaction of monolignol radicals in the presence of dirigent protein to form (+)-pinoresinolLignan biosynthesis is catalysed by oxidative enzymes. In the test tube the reaction results in a heteregenous mixture of dimeric compounds. When dirigent protein is present during the reaction, one stereoisomer of one compound is highly enriched. Dirigent proteins appear to possess no oxidative radical forming activity of their own; in the absence of oxidative enzyme, no reaction will occur.Recently, a second, enantiocomplementary dirigent protein was identified in Arabidopsis thaliana, which directs enantioselective synthesis of (-)-pinoresinol."@en }
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- Dirigent_protein abstract "Dirigent Proteins are members of a class of proteins which dictate the stereochemistry of a compound synthesized by other enzymes. The first dirigent protein was discovered in Forsythia intermedia. This protein has been found to direct the stereoselective biosynthesis of (+)-pinoresinol from coniferyl alcohol monomers:Reaction of monolignol radicals in the presence of dirigent protein to form (+)-pinoresinolLignan biosynthesis is catalysed by oxidative enzymes. In the test tube the reaction results in a heteregenous mixture of dimeric compounds. When dirigent protein is present during the reaction, one stereoisomer of one compound is highly enriched. Dirigent proteins appear to possess no oxidative radical forming activity of their own; in the absence of oxidative enzyme, no reaction will occur.Recently, a second, enantiocomplementary dirigent protein was identified in Arabidopsis thaliana, which directs enantioselective synthesis of (-)-pinoresinol.".
- Q5280773 abstract "Dirigent Proteins are members of a class of proteins which dictate the stereochemistry of a compound synthesized by other enzymes. The first dirigent protein was discovered in Forsythia intermedia. This protein has been found to direct the stereoselective biosynthesis of (+)-pinoresinol from coniferyl alcohol monomers:Reaction of monolignol radicals in the presence of dirigent protein to form (+)-pinoresinolLignan biosynthesis is catalysed by oxidative enzymes. In the test tube the reaction results in a heteregenous mixture of dimeric compounds. When dirigent protein is present during the reaction, one stereoisomer of one compound is highly enriched. Dirigent proteins appear to possess no oxidative radical forming activity of their own; in the absence of oxidative enzyme, no reaction will occur.Recently, a second, enantiocomplementary dirigent protein was identified in Arabidopsis thaliana, which directs enantioselective synthesis of (-)-pinoresinol.".