Matches in DBpedia 2015-10 for { ?s ?p "The term "gauche" refers to conformational isomers (conformers) where two vicinal groups are separated by a 60° torsion angle. IUPAC defines groups as gauche if they have a "synclinal alignment of groups attached to adjacent atoms".In stereochemistry, gauche interactions hinder bond rotation. For example, sighting along the C2–C3 bond in staggered butane, there are two possible relative potential energies."@en }
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- Gauche_effect comment "The term "gauche" refers to conformational isomers (conformers) where two vicinal groups are separated by a 60° torsion angle. IUPAC defines groups as gauche if they have a "synclinal alignment of groups attached to adjacent atoms".In stereochemistry, gauche interactions hinder bond rotation. For example, sighting along the C2–C3 bond in staggered butane, there are two possible relative potential energies.".