Matches in DBpedia 2015-10 for { ?s ?p "The Guerbet reaction, named after Marcel Guerbet (1861–1938), is an organic reaction converting a primary aliphatic alcohol into its β-alkylated dimer alcohol with loss of one equivalent of water. This reaction requires a catalyst and elevated temperatures.The original 1899 publication concerned the conversion of n-butanol to 2-ethyl-1-hexanol. The alcohols derived from this reaction are called Guerbet alcohols. Application of long-chained aliphatic alcohols gives access to surfactants.The reaction requires alkali metal hydroxides or alkoxides and hydrogenation catalysts such as Raney Nickel at higher temperature (220 °C) and pressure."@en }
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- Guerbet_reaction abstract "The Guerbet reaction, named after Marcel Guerbet (1861–1938), is an organic reaction converting a primary aliphatic alcohol into its β-alkylated dimer alcohol with loss of one equivalent of water. This reaction requires a catalyst and elevated temperatures.The original 1899 publication concerned the conversion of n-butanol to 2-ethyl-1-hexanol. The alcohols derived from this reaction are called Guerbet alcohols. Application of long-chained aliphatic alcohols gives access to surfactants.The reaction requires alkali metal hydroxides or alkoxides and hydrogenation catalysts such as Raney Nickel at higher temperature (220 °C) and pressure.".